Heterogeneous catalyst engineering ⇒ from stable and deactivation resistant to viable technical catalyst

Problem statement

Advances in heterogeneous catalyst “structure” are driven to improve their “function” or performance, i.e., activity, selectivity, and stability. Cooperative research is required to understand the structure and function relationships: developing new synthesis protocols for heterogeneous catalysts with unique surface properties, defined porosity, identification and understanding of catalytically active sites, reaction mechanisms, and finally, prediction and analysis of the processes using various computational tools.

Our group focuses on developing new catalyst formulations using innovative synthesis routes for various important heterogeneous catalysts. That includes thermal, electro, and bio-electro catalysis.

The active phase cannot be used directly in its final application or reactor for various reasons, including poor mechanical resistance, heat or mass transport, and fluidization features. We must mix the active phase with other ingredients in a matrix of binder and filler, while we shape it into a technical catalyst. We investigate new synthetic protocols for technical catalysis using spray drying and fluidized beds to cover the whole range of sizes. At the same time, we incorporate additional (unconventional) ingredients such as SiC to improve some features even further.

Goals

  • Technical catalyst I ⇒ spray drying and extrusion
  • Technical catalyst II ⇒ spray fluidized bed reactor
  • Technical catalyst III ⇒ electrospinning
  • Zeolite catalysts ⇒ with defined structure/porosity
  • Multi-metal (high entropy) alloy catalysts
  • MXene catalysts ⇒ single and multi-dimensional
  • Perovskite catalysts
  • Metal-organic framework (MOFs) catalysts
  • Supported metal/metal-oxide catalysts
  • Aerogel catalyst

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Related Publications

Influence of the Support on the Deactivation of Bifunctional Catalysts (Pt-Pd/Support) in the Hydrocracking of LCO
Chem. Eng. Trans. Year: 2011
Authors: Gutierrez, Arandes, Castaño, Aguayo, Bilbao
  • W2C
  • HCE
  • HPC
Inhibition of CoMo/HMS Catalyst Deactivation in the HDS of 4,6-DMDBT by Support Modification with Phosphate
Fuel Year: 2011
Authors: Nava, Infantes-Molina, Castaño, Guil-Lopez, Pawelec
  • HPC
  • HCE
Role of Acidity in the Deactivation and Steady Hydroconversion of Light Cycle Oil on Noble Metal Supported Catalysts
Energy & Fuels Year: 2011
Authors: Gutierrez, Arandes, Castaño, Aguayo, Bilbao
  • HCE
  • HPC
  • W2C
Hydrodesulfurization of Dibenzothiophene and a SRGO on Sulfide Ni(Co)Mo/Al2O3 Catalysts. Effect of Ru and Pd Promotion
Catal. Today Year: 2009
Authors: Navarro, Castaño, Alvarez-Galvan, Pawelec
  • HCE
  • HPC
Effect of the Support Acidity on the Aromatic Ring-Opening of Pyrolysis Gasoline over Pt/HZSM-5. Catalysts
Catal. Today Year: 2009
Authors: Castaño, Gutierrez, Villanueva, Pawelec, Arandes
  • W2C
  • HCE
  • HPC
Upgrading of Bio-Liquids on Different Mesoporous Silica-Supported CoMo Catalysts
Appl. Catal. B: Environ. Year: 2009
Authors: Nava, Pawelec, Castaño, Alvarez-Galvan, Loricera, Fierro
  • HPC
  • HCE
  • W2C
Enhancement of Biphenyl Hydrogenation over Gold Catalysts Supported on Fe-, Ce- and Ti-modified Mesoporous Silica (HMS)
J. Catal. Year: 2009
Authors: Castaño, Zepeda, Pawelec, Makkee, Fierro
  • HPC
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The Role of Zeolite Acidity in Coupled Toluene Hydrogenation and Ring-Opening in One and Two Steps
Ind. Eng. Chem. Res. Year: 2008
Authors: Castaño, Pawelec, Aguayo, Gatyubo, Arandes
  • HCE
  • HPC
  • FCC
Effect of the Catalyst Properties in Polypropylene Pyrolysis Waxes Cracking under FCC Conditions
Catal. Today Year: 2008
Authors: Arandes, Torre, Azkoiti, Castaño, Bilbao, De Lasa
  • FCC
  • W2C
  • HCE