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Catalytic decomposition of H₂S for H₂ generation 


    Problem Statement

    Hydrogen sulfide (H₂S) is a toxic and corrosive substance that is either naturally in aqueous or gas form or can be generated by industrial processes (e.g., in the petroleum industry). Globally, H₂S production (from both petroleum and natural sources) has reached 10 million tons annually, which will increase further. Using H₂S sources as feedstock for H₂ generation is a promising approach for eliminating H₂S and producing clean energy. The thermal decomposition of H₂S could be attractive from an economic standpoint. However, this process has several challenges, including thermodynamic limitations (high operating temperature, equilibrium limitation, and low conversion rate). Catalytic decomposition of H₂S for H₂ generation has drawn significant attention as an alternative process for H₂ generation at lower operating temperatures.

    We aim to develop, synthesize, characterize, and test innovative catalysts with promoted lifetime, activity, and selectivity for H₂ generation via the thermo-catalytic decomposition of hydrogen sulfide (H₂S).

      AMD

      Goals

      • Develop novel catalysts with high catalytic performance with long-term stability
      • Introduce simple, easy, and cost-effective techniques for enhancing catalyst properties
      • Explore metal alloy catalysts for the process
      • Analyze different process conditions to optimize hydrogen production
      • Develop advanced structure-function-deactivation relationships of the suitable catalysts

      Related People

      Related Publications

      Designing sulfide catalysts for H2S dissociation to H2 based on reaction descriptors and microkinetics
      Appl. Catal. B: Environ. Year: 2025 DOI:https://doi.org/10.1016/j.apcatb.2024.124605
      Authors: Almofleh, Alaithan, Velisoju, Mukhambetov, Lezcano, Aljama, Mohamed, Castaño
      • S2H
      • MKM
      • CRE