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Upgrading renewables, secondary, and waste streams through innovative hydroprocessing catalysts and reaction pathways


    Problem Statement

    Hydroprocessing is a well-implemented and versatile refinery conversion strategy, comprising a wide array of reaction routes such as: (i) hydrotreating, aiming for the hydrogenation of unsaturated hydrocarbons and the removal (hydrogenolysis) of heteroatoms such as sulfur or nitrogen; (ii) hydrocracking, for promoting C–C bond scission and the partial saturation of aromatics; or (iii) hydrodeoxygenation, for the specific removal of oxygen moieties. In this project, we investigate the conversion of highly polyaromatic feedstock like heavy fuel oil (HFO), pyrolysis fuel oil (PFO), or bio-oils from different biomass sources (i.e., agricultural waste, algae) for quality improvement and obtaining products with higher added value.

    We seek new (thermo-) catalytic strategies and improved heterogeneous catalysts with increased activity and stability. We put advanced analytical characterization techniques (i.e., nuclear magnetic resonance, high-res mass spectrometry) to work and combine their results with modeling and statistical tools.

    HPC

    Goals

    • Develop a quantitative analytical workflow to analyze and interpret these complex reacting environments
    • Explore novel renewable and waste resources to obtain chemicals and fuels
    • Deploy ad-hoc catalysts and process conditions to incorporate these wastes in the refinery (bio- and waste-refinery)
    • Analyze process dynamics and kinetics

    Related People

    Related Publications

    Designing Supported ZnNi Catalysts for the Removal of Oxygen from Bio-Liquids and Aromatics from Diesel
    Green Chem. Year: 2012
    Authors: Loricera, Castaño, Infantes-Molina, Hita, Gutierrez, Arandes, Fierro, Pawelec
    • HCE
    • HPC
    Influence of the Support on the Deactivation of Bifunctional Catalysts (Pt-Pd/Support) in the Hydrocracking of LCO
    Chem. Eng. Trans. Year: 2011
    Authors: Gutierrez, Arandes, Castaño, Aguayo, Bilbao
    • W2C
    • HCE
    • HPC
    Inhibition of CoMo/HMS Catalyst Deactivation in the HDS of 4,6-DMDBT by Support Modification with Phosphate
    Fuel Year: 2011
    Authors: Nava, Infantes-Molina, Castaño, Guil-Lopez, Pawelec
    • HPC
    • HCE
    Role of Acidity in the Deactivation and Steady Hydroconversion of Light Cycle Oil on Noble Metal Supported Catalysts
    Energy & Fuels Year: 2011
    Authors: Gutierrez, Arandes, Castaño, Aguayo, Bilbao
    • HCE
    • HPC
    • W2C
    Effect of Hydrogen on the Cracking Mechanisms of Cycloalkanes over Zeolites
    Catal. Today Year: 2010
    Authors: Castaño, Arandes, Olazar, Bilbao, Pawelec, Sedran
    • FCC
    • HPC
    • MKM
    Kinetic and Deactivation Modelling of Biphenyl Liquid-Phase Hydrogenation over Bimetallic Pt-Pd Catalyst
    Appl. Catal. B: Environ. Year: 2009
    Authors: Castaño, Van Herk, Kreutzer, Moulijn, Makkee
    • HPC
    • MKM
    Hydrodesulfurization of Dibenzothiophene and a SRGO on Sulfide Ni(Co)Mo/Al2O3 Catalysts. Effect of Ru and Pd Promotion
    Catal. Today Year: 2009
    Authors: Navarro, Castaño, Alvarez-Galvan, Pawelec
    • HCE
    • HPC
    Effect of the Support Acidity on the Aromatic Ring-Opening of Pyrolysis Gasoline over Pt/HZSM-5. Catalysts
    Catal. Today Year: 2009
    Authors: Castaño, Gutierrez, Villanueva, Pawelec, Arandes
    • W2C
    • HCE
    • HPC
    Catalyst Testing in a Multiple-Parallel, Gas-Liquid, Powder-Packed Bed Microreactor
    Appl. Catal. A: Gen. Year: 2009
    Authors: Van Herk, Castaño, Makkee, Moulijn, Kreutzer
    • HPC
    • CRE