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Upgrading renewables, secondary, and waste streams through innovative hydroprocessing catalysts and reaction pathways


    Problem Statement

    Hydroprocessing is a well-implemented and versatile refinery conversion strategy, comprising a wide array of reaction routes such as: (i) hydrotreating, aiming for the hydrogenation of unsaturated hydrocarbons and the removal (hydrogenolysis) of heteroatoms such as sulfur or nitrogen; (ii) hydrocracking, for promoting C–C bond scission and the partial saturation of aromatics; or (iii) hydrodeoxygenation, for the specific removal of oxygen moieties. In this project, we investigate the conversion of highly polyaromatic feedstock like heavy fuel oil (HFO), pyrolysis fuel oil (PFO), or bio-oils from different biomass sources (i.e., agricultural waste, algae) for quality improvement and obtaining products with higher added value.

    We seek new (thermo-) catalytic strategies and improved heterogeneous catalysts with increased activity and stability. We put advanced analytical characterization techniques (i.e., nuclear magnetic resonance, high-res mass spectrometry) to work and combine their results with modeling and statistical tools.

    HPC

    Goals

    • Develop a quantitative analytical workflow to analyze and interpret these complex reacting environments
    • Explore novel renewable and waste resources to obtain chemicals and fuels
    • Deploy ad-hoc catalysts and process conditions to incorporate these wastes in the refinery (bio- and waste-refinery)
    • Analyze process dynamics and kinetics

    Related People

    Related Publications

    Phosphorus-Containing Activated Carbon as Acid Support in a Bifunctional Pt-Pd Catalyst for Tire Oil Hydrocracking
    Cat. Comm. Year: 2016
    Authors: Hita, Cordero-Lanzac, Gallardo, Arandes, Rodriguez-Mirasol, Bilbao, Cordero, Castaño
    • HPC
    • W2C
    • HCE
    Petcoke-derived Functionalized Activated Carbon as Support in a Bifunctional Catalyst for Tire Oil Hydroprocessing
    Fuel Process. Technol. Year: 2016
    Authors: Hita, Palos, Arandes, Hill, Castaño
    • HPC
    • HCE
    • W2C
    Opportunities and Barriers for Producing High Quality Fuels from the Pyrolysis of Scrap Tires
    Renew. Sustain. Energy Rev. Year: 2016
    Authors: Hita, Arabiourrutia, Olazar, Bilbao, Arandes, Castaño
    Highly Cited Paper and Hot Paper according to Essential Science Indicators.
    • HPC
    • W2C
    • CRE
    • ANW
    Kinetic Modeling of the Hydrotreating and Hydrocracking Stages for Upgrading Scrap Tires Pyrolysis Oil (STPO) towards High Quality Fuels
    Energy & Fuels Year: 2015
    Authors: Hita, Aguayo, Olazar, Azkoiti, Bilbao, Arandes, Castaño
    • HPC
    • MKM
    • W2C
    Upgrading Model Compounds and Scrap Tires Pyrolysis Oil (STPO) on Hydrotreating NiMo Catalysts with Tailored Supports
    Fuel Year: 2015
    Authors: Hita, Gutierrez, Olazar, Bilbao, Arandes, Castaño
    • HPC
    • W2C
    • ANW
    • HCE
    Effect of Space Velocity on the Hydrocracking of Light Cycle Oil over a Pt-Pd/HY Zeolite Catalyst
    Fuel Process. Technol. Year: 2012
    Authors: Gutierrez, Arandes, Castaño, Olazar, Barona, Bilbao
    • HPC
    • MKM
    • W2C
    Preliminary Studies on Fuel Production Through LCO Hydrocracking on Noble-Metal Supported Catalysts
    Fuel Year: 2012
    Authors: Gutierrez, Arandes, Castaño, Olazar, Bilbao
    • HPC
    • HCE
    • W2C
    Deactivating Species Deposited on Pt-Pd Catalysts in the Hydrocracking of LCO
    Energy & Fuels Year: 2012
    Authors: Castaño, Gutierrez, Hita, Arandes, Aguayo, Bilbao
    • HPC
    • W2C
    • ANW
    Effect of Temperature in the Hydrocracking of LCO on Noble-Metal Supported Catalyst for Fuel Production
    Chem. Eng. Technol. Year: 2012
    Authors: Gutierrez, Arandes, Castaño, Olazar, Barona, Bilbao
    • HPC
    • MKM
    • W2C
    Enhancement of Aromatic Hydro-Upgrading on a Pt Catalyst by Promotion with Pd and Shape-Selective Support
    Fuel Process. Technol. Year: 2012
    Authors: Gutierrez, Arandes, Castaño, Olazar, Bilbao
    • HPC
    • HCE
    • W2C