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Process development and deployment for the direct reforming of crude oil to hydrogen and carbon materials


    Problem Statement

    Hydrogen is a clean energy source and carrier because of its non−polluting combustion, making it an excellent alternative to the current fossil fuel-dominated energy scenario. Nonetheless, there are several critical challenges to implementing a broad sustainable use of hydrogen. In this project, we develop a laboratory−scale setup with stable operation and high hydrogen production.

    We aim at assessing (i) different hydrocarbon feedstock (from n-heptane to crude oil) fed to the reactor with water as emulsions, carried by steam or vaporized; (ii) steam reforming (SR) and auto thermal reforming (ATR); and (iii) stable and energy efficient catalysts for the efficient production of hydrogen inside packed, fluidized, and multifunctional reactors. These, coupled with carbon capture technologies, minimize the carbon footprint of the overall process.

    We support our research with simulations and techno−economic analysis to assess the approach's feasibility. C2H can use the current refinery infrastructure to reduce costs and the impact of market volatility on refinery operations.

    C2H-REF

    Goals

    • Develop and scale up advanced catalysts and reactors for converting crude to hydrogen
    • Model process simulations to analyze the viability of the process 
    • Scaling the technical catalysts for their demanding application: endothermic process, poisoning, massive coke deposition, and fluidized-bed reactors
    • Analyze different process conditions to optimize hydrogen production and stability in the process

    Related People

    Related Publications

    Coking and Sintering Progress of a Ni Supported Catalyst in the Steam Reforming of Biomass Pyrolysis Volatiles
    Appl. Catal. B: Environ. Year: 2018
    Authors: Ochoa, Arregi, Amutio, Gayubo, Olazar, Bilbao, Castaño
    • REF
    • W2C
    • ANW
    • CRE
    Role of Oxygenates and Effect of Operating Conditions in the Deactivation of a Ni Supported Catalyst During the Steam Reforming of Bio-oil
    Green Chem. Year: 2017
    Authors: Ochoa, Aramburu, Valle, Resasco, Bilbao, Gayubo, Castaño
    Green Chemistry Hot Articles.
    • REF
    • W2C
    • ANW
    • MKM
    Assessment of Thermogravimetric Methods for Calculating Coke Combustion-Regeneration Kinetics of Deactivated Catalyst
    Chem. Eng. Sci. Year: 2017
    Authors: Ochoa, Ibarra, Bilbao, Arandes, Castaño
    • O2H
    • OLG
    • CHA
    • FCC
    • REF
    • MKM
    Deactivation Dynamics of a Ni Supported Catalyst during the Steam Reforming of Volatiles from Waste Polyethylene Pyrolysis
    Appl. Catal. B: Environ. Year: 2017
    Authors: Ochoa, Barbarias, Artetxe, Gayubo, Olazar, Bilbao, Castaño
    • REF
    • W2C
    • ANW
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    Prospects for Obtaining High Quality Fuels from the Hydrocracking of a Hydrotreated Scrap Tires Pyrolysis Oil
    Energy & Fuels Year: 2015
    Authors: Hita, Rodriguez, Olazar, Bilbao, Arandes, Castaño
    • W2C
    • REF
    • ANW
    Compositional Insights and Valorization Pathways for the Carbonaceous Material Deposited during Bio-Oil Thermal Treatment
    ChemSusChem Year: 2014
    Authors: Ochoa, Aramburu, Ibanez, Valle, Bilbao, Gayubo, Castaño
    • REF
    • W2C
    • ANW
    Effect of Pressure on the Hydrocracking of Light Cycle Oil with a Pt-Pd/HY Catalyst
    Energy & Fuels Year: 2012
    Authors: Gutierrez, Arandes, Castaño, Olazar, Bilbao
    • REF
    • W2C
    Coke formation and deactivation during catalytic reforming of biomass and waste pyrolysis products: A review
    Renew. Sustain. Energy Rev. Year: 2020
    Authors: Ochoa, Bilbao, Gayubo, Castaño
    • REF
    • W2C
    • ANW
    • CRE