Catalytic reactor engineering ⇒ information-driven design of packed (operando), fluidized, multi-functional, and -phase reactors

Problem statement

At lab-scale, the ultimate goal of a catalytic reactor is to provide (1) reliable kinetic information, neglecting or controlling other phenomena (heat-mass transfer and hydrodynamics); (2) high-throughput data to amplify the results, accelerate model and catalyst discoveries; and (3) results with the minimum requirements of reactants and wastes generated. The pillars of these reactors are quality, quantity, and safety.

We design, build and test different laboratory-scale reactors. Our strategy involves creating and testing reactor prototypes while modeling these using our workflow. We have high-speed cameras, probes, and other measuring instruments to understand the reactor behavior. We focus on packed-, fluidized-bed, and multiphase reactors:

In packed bed reactors, we focus on forced dynamic and operando reactors. These are the quintessence of information-driven reactors where the dynamics can involve flow changes, temperature, pressure, partial pressure, presence of activity modifiers (poissons, H2O…). In operando reactors, we follow a spectro-kinetic-deactivation-hydrodynamic approach to resolve the individual steps involved. In fluidized bed reactors, we focus on downers and multifunctional reactors (circulating, multizone or two-zone, Berty reactors) We focus on trickle-bed, slurry, and bio-electrochemical reactors in multiphase bed reactors.

Al pilot-plant scale, we aim to reach the maximum productivity levels while solving the growing pains: the scale-up. Based on a robust kinetic model obtained in the intrinsic kinetic reactor (lab-scale) and using computational fluid dynamics, we design, build, and operate pilot plants. At this stage, we seek partnerships with investment or industrial enterprises to make these pilot plants.

Goals

  • Multifunctional fluidized bed reactors ⇒ multizone, circulating...
  • Packed bed membrane reactors
  • Forced dynamic reactors ⇒ pulsing, SSITKA...
  • Forced dynamic operando reactors ⇒ DRIFTS, TPSR...
  • Operando reactors
  • Spray fluidized bed reactors
  • Downer reactor I ⇒ micro downer
  • Downer reactor II ⇒ counter-current and scale-up
  • Batch Berty reactor ⇒ short contact time
  • Multiphase reactors ⇒ trickle bed and slurry
  • High throughput experimentation (HTE) reactors
  • Photo-thermal and bioreactors
  • Reactor visualization and prototyping lab
  • Spatio-temporal hydrodynamic characterization and validation

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Related Covers

Related Publications

Comparative analysis of counter-current and co-current downer reactors using particle image velocimetry and computational particle-fluid dynamics

by Aldugman, Cui, Alzailaie, Alhareth, Langley, Alfilfil, Almajnouni, Gascon, Thoroddsen, Castaño
Chem. Eng. J. Adv. Year: 2025 DOI: https://doi.org/10.1016/j.ceja.2024.100687

Abstract

We investigated the hydrodynamics in co- and counter-current downer operations using particle image velocimetry (PIV) and computational particle fluid dynamics simulations (CPFD). Pilot-scale experiments were conducted for fluid catalytic cracking (FCC) catalysts and sand, which verified the system stability and provided the validation basis for the simulation strategy. We compared the reactor characteristics of counter-current and co-current downers under different operating modes and conditions using PIV experiments and CPFD simulations. PIV experiments showed that the counter-current downer exhibits a more uniform particle velocity profile, with a gradient of only 8 % of the maximum velocity, compared to the co-current operation, which shows a significantly steeper gradient of 39.5 % from the maximum. Simulations confirmed that the counter-current downer reactor has 69 % higher solid holdup and 98 % longer residence time than the co-current operation. Thus, the counter-current downer reactor demonstrated intermediate behavior between the classical co-current downer and riser reactors, offering flexibility for industrial applications.

Keywords

C2C FCC MKM CRE