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Upgrading renewables, secondary, and waste streams through innovative hydroprocessing catalysts and reaction pathways

Problem statement

Hydroprocessing is a well-implemented and versatile refinery conversion strategy, comprising a wide array of reaction routes such as: (i) hydrotreating, aiming for the hydrogenation of unsaturated hydrocarbons and the removal (hydrogenolysis) of heteroatoms such as sulfur or nitrogen; (ii) hydrocracking, for promoting Cā€“C bond scission and the partial saturation of aromatics; or (iii) hydrodeoxygenation, for the specific removal of oxygen moieties. In this project, we investigate the conversion of highly polyaromatic feedstock like heavy fuel oil (HFO), pyrolysis fuel oil (PFO), or bio-oils from different biomass sources (i.e., agricultural waste, algae) for quality improvement and obtaining products with higher added value.

We seek new (thermo-) catalytic strategies and improved heterogeneous catalysts with increased activity and stability. We put advanced analytical characterization techniques (i.e., nuclear magnetic resonance, high-res mass spectrometry) to work and combine their results with modeling and statistical tools.

Goals

  • Develop a quantitative analytical workflow to analyze and interpret these complex reacting environments
  • Explore novel renewable and waste resources to obtain chemicals and fuels
  • Deploy ad-hoc catalysts and process conditions to incorporate these wastes in the refinery (bio- and waste-refinery)
  • Analyze process dynamics and kinetics
HPC

Related People

Related Publications

Kinetic Modeling of the Hydrotreating and Hydrocracking Stages for Upgrading Scrap Tires Pyrolysis Oil (STPO) towards High Quality Fuels
Energy & Fuels Year: 2015
Authors: Hita, Aguayo, Olazar, Azkoiti, Bilbao, Arandes, Castaño
  • HPC
  • MKM
  • W2C
Upgrading Model Compounds and Scrap Tires Pyrolysis Oil (STPO) on Hydrotreating NiMo Catalysts with Tailored Supports
Fuel Year: 2015
Authors: Hita, Gutierrez, Olazar, Bilbao, Arandes, Castaño
  • HPC
  • W2C
  • ANW
  • HCE
Effect of Space Velocity on the Hydrocracking of Light Cycle Oil over a Pt-Pd/HY Zeolite Catalyst
Fuel Process. Technol. Year: 2012
Authors: Gutierrez, Arandes, Castaño, Olazar, Barona, Bilbao
  • HPC
  • MKM
  • W2C
Preliminary Studies on Fuel Production Through LCO Hydrocracking on Noble-Metal Supported Catalysts
Fuel Year: 2012
Authors: Gutierrez, Arandes, Castaño, Olazar, Bilbao
  • HPC
  • HCE
  • W2C
Deactivating Species Deposited on Pt-Pd Catalysts in the Hydrocracking of LCO
Energy & Fuels Year: 2012
Authors: Castaño, Gutierrez, Hita, Arandes, Aguayo, Bilbao
  • HPC
  • W2C
  • ANW
Effect of Temperature in the Hydrocracking of LCO on Noble-Metal Supported Catalyst for Fuel Production
Chem. Eng. Technol. Year: 2012
Authors: Gutierrez, Arandes, Castaño, Olazar, Barona, Bilbao
  • HPC
  • MKM
  • W2C
Enhancement of Aromatic Hydro-Upgrading on a Pt Catalyst by Promotion with Pd and Shape-Selective Support
Fuel Process. Technol. Year: 2012
Authors: Gutierrez, Arandes, Castaño, Olazar, Bilbao
  • HPC
  • HCE
  • W2C
Designing Supported ZnNi Catalysts for the Removal of Oxygen from Bio-Liquids and Aromatics from Diesel
Green Chem. Year: 2012
Authors: Loricera, Castaño, Infantes-Molina, Hita, Gutierrez, Arandes, Fierro, Pawelec
  • HCE
  • HPC
Influence of the Support on the Deactivation of Bifunctional Catalysts (Pt-Pd/Support) in the Hydrocracking of LCO
Chem. Eng. Trans. Year: 2011
Authors: Gutierrez, Arandes, Castaño, Aguayo, Bilbao
  • W2C
  • HCE
  • HPC
Inhibition of CoMo/HMS Catalyst Deactivation in the HDS of 4,6-DMDBT by Support Modification with Phosphate
Fuel Year: 2011
Authors: Nava, Infantes-Molina, Castaño, Guil-Lopez, Pawelec
  • HPC
  • HCE