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Controlling selectivity and stability of zeolite catalysts for methanol to hydrocarbons and ethylene oligomerization

Problem statement

Olefins are commodity chemicals with applications in the production of plastics (petrochemical industry), lubricants, plasticizers, and surfactants, among many others. However, there is an imbalance between their production and demand, which oligomerization-cracking reactions over zeolites could solve. At the same time, zeolites are excellent catalysts for methanol to hydrocarbons (MTH), olefins (MTO), or aromatics (MTA). The processes aim to produce light hydrocarbons like propylene or convert ethylene into higher-value a-olefins, aromatic hydrocarbons (BTX), and jet fuel.

Our focus in this project is to modify, synthesize and develop novel materials of different porosity (engineered at the multiscale): from hierarchical zeolites, nano zeolites, and hollow zeolites to catalytic particles, bodies, spray-dried and extrudates with tuned properties. Additionally, we incorporate different metals (i.e., Ni, Cr, Zn) to adjust the selectivity of desired products.

We use various reactors, such as operando or high-throughput packed-bed and batch reactors.

Goals

  • Develop a quantitative analytical workflow to analyze and interpret these complex reacting environments
  • Explore novel renewable and waste resources to obtain chemicals and fuels
  • Deploy ad-hoc catalysts and process conditions to incorporate these wastes in the refinery (bio- and waste-refinery)
  • Analyze process dynamics and kinetics
OLG2023

Related People

Hend Omar Mohamed
Kiruthika Jayaseelan
Rushana Khairova

Related Publications

The intrinsic effect of co-feeding water on the formation of active/deactivating species in the methanol-to-hydrocarbons reaction on ZSM-5 zeolite

by Valecillos, Elordi, Aguayo, Castaño
Catal. Sci. Technol. Year: 2021

Abstract

Water is formed and added in the conversion of methanol-to-hydrocarbons, slowing down both the reaction and deactivation rates. This work aims to clarify the selective nature of water quenching on a ZSM-5 zeolite catalyst in terms of (1) reaction/deactivation using an integral reactor (full range of conversions) and (2) rate of formation/growth of deactivating species using two FTIR and UV-vis in situ differential reactors (conversions lower than 0.15). Our approach assesses the effect of water under comparable conversion conditions while characterizing in detail the products and intermediates of the reaction (by online and in situanalysis, and extraction measurements). The results obtained prove, in an unbiased way, that water quenches more selectively the deactivation than the reaction with moderate amounts of added water (water/methanol = 0.11 g g−1). On the other hand, in situ FTIR spectroscopy evidences that co-feeding water sweeps the retained species from the silanol sites and favors the formation of olefins as retained species, while in situ UV-vis spectroscopy proves that the rate of formation/growth of discrete retained species drop by the addition of water and the degree of this decline is severer for coke than for coke precursors or active species.

Keywords

O2H