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Reactor design and optimization for converting crude (and refinery wastes) to chemicals in one step through steam-fluidized catalytic cracking

Problem statement

The direct catalytic cracking from crude oil to chemicals could dominate the petrochemical industry shortly, with less fuel consumption and increasing production of light olefins and aromatics. We aim to simplify the refinery into a unique one-step conversion scheme, targeting the production of the most demanded petrochemicals.

Using a bottom-up holistic approach, we design a catalytic crude-to-chemicals process toward this goal using a bottom-up holistic approach. We investigate advanced reactors with intrinsic kinetic data and controlled hydrodynamics to improve the process. We study the non-linear multiscale phenomena by coupling the hydrodynamics, heat transfer, and reaction kinetics.

We use particle image/tracking velocimetry experiments, kinetic modeling, computational particle fluid dynamic modeling, and optimization approaches to improve operating scenarios and develop innovative reactor prototypes.

We focus on the catalyst, reactor, and process levels for system enhancement and intensification. We are optimizing several state-of-the-art laboratory and pilot-scale units, including a circulating Berty, downer, and multifunctional fluidized bed reactors.

Goals

  • Develop and scale up advanced reactors for converting crude oil to chemicals through fluid catalytic cracking approaching intrinsic kinetics
  • Model process dynamics using reactive particle fluid dynamics coupled with experimental validations
  • Establish a design workflow for short-contact time reactors based on modeling, prototyping, and testing
  • Analyze the novel process developments in fluid catalytic cracking: novel feedstock, process modifications…
C2C-FCC2023

Related People

Related Publications

Assessment of Thermogravimetric Methods for Calculating Coke Combustion-Regeneration Kinetics of Deactivated Catalyst
Chem. Eng. Sci. Year: 2017
Authors: Ochoa, Ibarra, Bilbao, Arandes, Castaño
  • O2H
  • OLG
  • CHA
  • FCC
  • REF
  • MKM
Dual Coke Deactivation Pathways during the Catalytic Cracking of Raw Bio-Oil and Vacuum Gasoil in FCC Conditions
Appl. Catal. B: Environ. Year: 2016
Authors: Ibarra, Veloso, Bilbao, Arandes, Castaño
Open Access.
  • O2H
  • FCC
  • W2C
  • MKM
Identification of the coke deposited on an HZSM-5 zeolite catalyst during the sequenced pyrolysis-cracking of HDPE
Appl. Catal. B: Environ. Year: 2014
Authors: Ibanez, Artetxe, Lopez, Elordi, Bilbao, Olazar, Castaño
  • FCC
  • W2C
  • ANW
Deactivating Species in the Transformation of Crude Bio-Oil with Methanol into Hydrocarbons on a HZSM-5 Catalyst
J. Catal. Year: 2012
Authors: Valle, Castaño, Olazar, Bilbao, Gayubo
  • O2H
  • FCC
  • W2C
  • ANW
Effect of the Acidity of the HZSM-5 Zeolite Catalyst on the Cracking of High Density Polyethylene
Appl. Catal. A: Gen. Year: 2012
Authors: Elordi, Olazar, Artetxe, Castaño, Bilbao
  • FCC
  • W2C
  • HCE
Pathways of Coke Formation on an MFI Catalyst during the Cracking of Waste Polyolefins
Catal. Sci. Technol. Year: 2012
Authors: Castaño, Elordi, Ibanez, Olazar, Bilbao
  • FCC
  • W2C
  • ANW
  • MKM
Polyethylene Cracking on a Spent FCC Catalyst in a Conical Spouted Bed
Ind. Eng. Chem. Res. Year: 2012
Authors: Elordi, Olazar, Castaño, Artetxe, Bilbao
  • FCC
  • W2C
  • CRE
Role of Pore Structure in the Deactivation of Zeolites (HZSM-5, Hbeta and HY) by Coke in the Pyrolysis of Polyethylene in a Conical Spouted Bed Reactor
Appl. Catal. B: Environ. Year: 2011
Authors: Elordi, Olazar, Lopez, Castaño, Bilbao
  • FCC
  • W2C
  • ANW
  • HCE