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Reactor design and optimization for converting crude (and refinery wastes) to chemicals in one step through steam-fluidized catalytic cracking

Problem statement

The direct catalytic cracking from crude oil to chemicals could dominate the petrochemical industry shortly, with less fuel consumption and increasing production of light olefins and aromatics. We aim to simplify the refinery into a unique one-step conversion scheme, targeting the production of the most demanded petrochemicals.

Using a bottom-up holistic approach, we design a catalytic crude-to-chemicals process toward this goal using a bottom-up holistic approach. We investigate advanced reactors with intrinsic kinetic data and controlled hydrodynamics to improve the process. We study the non-linear multiscale phenomena by coupling the hydrodynamics, heat transfer, and reaction kinetics.

We use particle image/tracking velocimetry experiments, kinetic modeling, computational particle fluid dynamic modeling, and optimization approaches to improve operating scenarios and develop innovative reactor prototypes.

We focus on the catalyst, reactor, and process levels for system enhancement and intensification. We are optimizing several state-of-the-art laboratory and pilot-scale units, including a circulating Berty, downer, and multifunctional fluidized bed reactors.

Goals

  • Develop and scale up advanced reactors for converting crude oil to chemicals through fluid catalytic cracking approaching intrinsic kinetics
  • Model process dynamics using reactive particle fluid dynamics coupled with experimental validations
  • Establish a design workflow for short-contact time reactors based on modeling, prototyping, and testing
  • Analyze the novel process developments in fluid catalytic cracking: novel feedstock, process modifications…
C2C-FCC2023

Related People

Related Publications

Imaging the Profiles of Deactivating-Species on the Catalyst Used for the Cracking of Waste Polyethylene by Combined Microscopies

by Castaño, Elordi, Olazar, Bilbao
ChemCatChem Year: 2012

Abstract

The catalytic cracking of high‐density polyethylene (HDPE) is an attractive process to valorize wastes throughout the production of the original monomers or fuels.1 The cracking catalyst based on zeolites is able to drive the scission of the polymeric chain, while controlling the final selectivity of monomers or fuels.2 The disadvantage of using a cracking catalyst is the deactivation caused by coke fouling, which hinders the cracking of heavy hydrocarbons and reduces the lifetime of the catalyst.3

Keywords

FCC W2C ANW