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Reactor design and optimization for converting crude (and refinery wastes) to chemicals in one step through steam-fluidized catalytic cracking

Problem statement

The direct catalytic cracking from crude oil to chemicals could dominate the petrochemical industry shortly, with less fuel consumption and increasing production of light olefins and aromatics. We aim to simplify the refinery into a unique one-step conversion scheme, targeting the production of the most demanded petrochemicals.

Using a bottom-up holistic approach, we design a catalytic crude-to-chemicals process toward this goal using a bottom-up holistic approach. We investigate advanced reactors with intrinsic kinetic data and controlled hydrodynamics to improve the process. We study the non-linear multiscale phenomena by coupling the hydrodynamics, heat transfer, and reaction kinetics.

We use particle image/tracking velocimetry experiments, kinetic modeling, computational particle fluid dynamic modeling, and optimization approaches to improve operating scenarios and develop innovative reactor prototypes.

We focus on the catalyst, reactor, and process levels for system enhancement and intensification. We are optimizing several state-of-the-art laboratory and pilot-scale units, including a circulating Berty, downer, and multifunctional fluidized bed reactors.

Goals

  • Develop and scale up advanced reactors for converting crude oil to chemicals through fluid catalytic cracking approaching intrinsic kinetics
  • Model process dynamics using reactive particle fluid dynamics coupled with experimental validations
  • Establish a design workflow for short-contact time reactors based on modeling, prototyping, and testing
  • Analyze the novel process developments in fluid catalytic cracking: novel feedstock, process modifications…
C2C-FCC2023

Related People

Related Publications

Effect of Operating Conditions on the Coke Nature and HZSM-5 Catalysts Deactivation in the Transformation of Crude Bio-Oil into Hydrocarbons

by Ibanez, Valle, Bilbao, Gayubo, Castaño
Catal. Today Year: 2012

Abstract

A study has been carried out on the effect of operating conditions (bio-oil/methanol ratio in the feed, temperature) on the deactivation of HZSM-5 catalysts used in the production of hydrocarbons by catalytic conversion of crude bio-oil continuously fed into a fluidized bed reactor. The bio-oil to be fed into the reactor has previously been subjected to an on-line thermal transformation in which the pyrolytic lignin derivatives have been re-polymerized. The coke deposited on the catalyst has been studied using different analytical techniques (FTIR spectroscopy, MS/FTIR-TPO, 13C CP-MAS NMR spectroscopy). The results evidence a direct relationship between coke deposition and deactivation and the concentration of bio-oil oxygenates in the reaction medium. Consequently, bio-oil conversion should be promoted in order to mitigate coke deposition. This is achieved using a HZSM-5 zeolite catalyst with a reduced SiO2/Al2O3 ratio and increasing reaction temperature and methanol/bio-oil ratio in the feed. The acidity of the HZSM-5 zeolite also has an influence on the nature of the coke, given that it contributes to increasing coke condensation towards polycondensed aromatic structures, although this has a minor effect on bio-oil conversion decrease with time on stream. The results obtained evidence the interest of the initiatives for co-feeding bio-oil with methanol to obtain hydrocarbons.

Keywords

O2H FCC W2C ANW