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Reactor design and optimization for converting crude (and refinery wastes) to chemicals in one step through steam-fluidized catalytic cracking

Problem statement

The direct catalytic cracking from crude oil to chemicals could dominate the petrochemical industry shortly, with less fuel consumption and increasing production of light olefins and aromatics. We aim to simplify the refinery into a unique one-step conversion scheme, targeting the production of the most demanded petrochemicals.

Using a bottom-up holistic approach, we design a catalytic crude-to-chemicals process toward this goal using a bottom-up holistic approach. We investigate advanced reactors with intrinsic kinetic data and controlled hydrodynamics to improve the process. We study the non-linear multiscale phenomena by coupling the hydrodynamics, heat transfer, and reaction kinetics.

We use particle image/tracking velocimetry experiments, kinetic modeling, computational particle fluid dynamic modeling, and optimization approaches to improve operating scenarios and develop innovative reactor prototypes.

We focus on the catalyst, reactor, and process levels for system enhancement and intensification. We are optimizing several state-of-the-art laboratory and pilot-scale units, including a circulating Berty, downer, and multifunctional fluidized bed reactors.

Goals

  • Develop and scale up advanced reactors for converting crude oil to chemicals through fluid catalytic cracking approaching intrinsic kinetics
  • Model process dynamics using reactive particle fluid dynamics coupled with experimental validations
  • Establish a design workflow for short-contact time reactors based on modeling, prototyping, and testing
  • Analyze the novel process developments in fluid catalytic cracking: novel feedstock, process modifications…
C2C-FCC2023

Related People

Related Publications

Implications of feeding or cofeeding bio-oil in the fluid catalytic cracker (FCC) in terms of regeneration kinetics and energy balance

by Ochoa, Vicente, Sierra, Arandes, Castaño
Energy Year: 2020 DOI: https://doi.org/10.1016/j.energy.2020.118467

Abstract

Feeding or cofeeding bio-oil (biomass pyrolysis oil) into the fluid catalytic cracking (FCC) has a direct impact on product distribution, reaction kinetics and deactivation of this key catalytic valorization strategy. In this work, we have analysed the impact in terms of the catalyst regeneration kinetics and energy balance of the unit. These factors are linked to the holistic viability of revamped refineries turned into biorefineries. Deactivated catalysts were obtained in FCC experiments using vacuum gasoil and raw bio-oil. The regeneration kinetics of coke combustion were analysed in a thermobalance, whereas the heats dissipated throughout the combustion (high heating values) were analysed in a calorimeter. Overall, the regenerator does not require major design amendments to treat bio-oil. We found a linear correlation between the higher heating value of the reactants and the coke produced, which enables to predict possible scenarios in the FCC unit. When incorporating higher amounts of bio-oil, the heat balance of the unit changes significantly: the temperature in the regenerator rises up to +36 K, requiring significant energy input for heating the bio-oil but offering the chance to recover more (electrical) energy when the proportion of bio-oil is greater than ca. 50%.

Keywords

FCC MKM