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Reactor design and optimization for converting crude (and refinery wastes) to chemicals in one step through steam-fluidized catalytic cracking

Problem statement

The direct catalytic cracking from crude oil to chemicals could dominate the petrochemical industry shortly, with less fuel consumption and increasing production of light olefins and aromatics. We aim to simplify the refinery into a unique one-step conversion scheme, targeting the production of the most demanded petrochemicals.

Using a bottom-up holistic approach, we design a catalytic crude-to-chemicals process toward this goal using a bottom-up holistic approach. We investigate advanced reactors with intrinsic kinetic data and controlled hydrodynamics to improve the process. We study the non-linear multiscale phenomena by coupling the hydrodynamics, heat transfer, and reaction kinetics.

We use particle image/tracking velocimetry experiments, kinetic modeling, computational particle fluid dynamic modeling, and optimization approaches to improve operating scenarios and develop innovative reactor prototypes.

We focus on the catalyst, reactor, and process levels for system enhancement and intensification. We are optimizing several state-of-the-art laboratory and pilot-scale units, including a circulating Berty, downer, and multifunctional fluidized bed reactors.

Goals

  • Develop and scale up advanced reactors for converting crude oil to chemicals through fluid catalytic cracking approaching intrinsic kinetics
  • Model process dynamics using reactive particle fluid dynamics coupled with experimental validations
  • Establish a design workflow for short-contact time reactors based on modeling, prototyping, and testing
  • Analyze the novel process developments in fluid catalytic cracking: novel feedstock, process modifications…
C2C-FCC2023

Related People

Related Publications

Effect of HZSM-5 Catalyst Addition on the Cracking of Polyolefin Pyrolysis Waxes under FCC Conditions

by Arandes, Azkoiti, Torre, Olazar, Castaño
Chem. Eng. J. Year: 2007

Abstract

A study has been carried out on the effect of catalyst acidity and composition (mixtures of base catalyst and catalysts provided with HZSM-5 zeolite of different acidity) on the catalytic cracking of polyolefin pyrolysis waxes carried out under standard conditions in a refinery FCC. The experiments have been carried out in a riser simulator, in the 500–550 °C range. The results show that the yields and composition of product stream are acceptable and controlable by refineries without any special adaptation of process conditions. The acidity of the catalysts has a relevant effect on hydrogen transfer capacity, which contributes to decreasing the concentration of olefins in the gases and in the gasoline. The incorporation of HZSM-5 zeolite is very efficient for increasing the yield of gasoline. This gasoline and LPG are more olefinic than those obtained with the base catalyst, given that hydrogen transfer capacity of the catalyst is inhibited.

Keywords

FCC W2C CRE