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Reactor design and optimization for converting crude (and refinery wastes) to chemicals in one step through steam-fluidized catalytic cracking

Problem statement

The direct catalytic cracking from crude oil to chemicals could dominate the petrochemical industry shortly, with less fuel consumption and increasing production of light olefins and aromatics. We aim to simplify the refinery into a unique one-step conversion scheme, targeting the production of the most demanded petrochemicals.

Using a bottom-up holistic approach, we design a catalytic crude-to-chemicals process toward this goal using a bottom-up holistic approach. We investigate advanced reactors with intrinsic kinetic data and controlled hydrodynamics to improve the process. We study the non-linear multiscale phenomena by coupling the hydrodynamics, heat transfer, and reaction kinetics.

We use particle image/tracking velocimetry experiments, kinetic modeling, computational particle fluid dynamic modeling, and optimization approaches to improve operating scenarios and develop innovative reactor prototypes.

We focus on the catalyst, reactor, and process levels for system enhancement and intensification. We are optimizing several state-of-the-art laboratory and pilot-scale units, including a circulating Berty, downer, and multifunctional fluidized bed reactors.

Goals

  • Develop and scale up advanced reactors for converting crude oil to chemicals through fluid catalytic cracking approaching intrinsic kinetics
  • Model process dynamics using reactive particle fluid dynamics coupled with experimental validations
  • Establish a design workflow for short-contact time reactors based on modeling, prototyping, and testing
  • Analyze the novel process developments in fluid catalytic cracking: novel feedstock, process modifications…
C2C-FCC2023

Related People

Related Publications

Comparative analysis of counter-current and co-current downer reactors using particle image velocimetry and computational particle-fluid dynamics

by Aldugman, Cui, Alzailaie, Alhareth, Langley, Alfilfil, Almajnouni, Gascon, Thoroddsen, Castaño
Chem. Eng. J. Adv. Year: 2025 DOI: https://doi.org/10.1016/j.ceja.2024.100687

Abstract

We investigated the hydrodynamics in co- and counter-current downer operations using particle image velocimetry (PIV) and computational particle fluid dynamics simulations (CPFD). Pilot-scale experiments were conducted for fluid catalytic cracking (FCC) catalysts and sand, which verified the system stability and provided the validation basis for the simulation strategy. We compared the reactor characteristics of counter-current and co-current downers under different operating modes and conditions using PIV experiments and CPFD simulations. PIV experiments showed that the counter-current downer exhibits a more uniform particle velocity profile, with a gradient of only 8 % of the maximum velocity, compared to the co-current operation, which shows a significantly steeper gradient of 39.5 % from the maximum. Simulations confirmed that the counter-current downer reactor has 69 % higher solid holdup and 98 % longer residence time than the co-current operation. Thus, the counter-current downer reactor demonstrated intermediate behavior between the classical co-current downer and riser reactors, offering flexibility for industrial applications.

Keywords

C2C FCC MKM CRE