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Reactor design and optimization for converting crude (and refinery wastes) to chemicals in one step through steam-fluidized catalytic cracking

Problem statement

The direct catalytic cracking from crude oil to chemicals could dominate the petrochemical industry shortly, with less fuel consumption and increasing production of light olefins and aromatics. We aim to simplify the refinery into a unique one-step conversion scheme, targeting the production of the most demanded petrochemicals.

Using a bottom-up holistic approach, we design a catalytic crude-to-chemicals process toward this goal using a bottom-up holistic approach. We investigate advanced reactors with intrinsic kinetic data and controlled hydrodynamics to improve the process. We study the non-linear multiscale phenomena by coupling the hydrodynamics, heat transfer, and reaction kinetics.

We use particle image/tracking velocimetry experiments, kinetic modeling, computational particle fluid dynamic modeling, and optimization approaches to improve operating scenarios and develop innovative reactor prototypes.

We focus on the catalyst, reactor, and process levels for system enhancement and intensification. We are optimizing several state-of-the-art laboratory and pilot-scale units, including a circulating Berty, downer, and multifunctional fluidized bed reactors.

Goals

  • Develop and scale up advanced reactors for converting crude oil to chemicals through fluid catalytic cracking approaching intrinsic kinetics
  • Model process dynamics using reactive particle fluid dynamics coupled with experimental validations
  • Establish a design workflow for short-contact time reactors based on modeling, prototyping, and testing
  • Analyze the novel process developments in fluid catalytic cracking: novel feedstock, process modifications…
C2C-FCC2023

Related People

Related Publications

Catalytic Cracking of Waxes Produced by the Fast Pyrolysis of Polyolefins

by Arandes, Torre, Castaño, Olazar, Bilbao
Energy & Fuels Year: 2007

Abstract

The cracking of the waxes obtained in the flash pyrolysis of polypropylene has been studied in laboratory FCC units under the standard conditions in FCC (fluid catalytic cracking) units. The reaction equipment is provided with a riser simulator reactor, and the experiments have been carried out using a commercial equilibrium catalyst, with a catalyst/feed ratio of C/O = 5.5, in the 500−550 °C range and for contact times between 3 and 12 s. The effect of these operating conditions on the yields of products and on the composition of gas and gasoline lumps has been studied. The results have been compared with those of VGO (vacuum gas oil) cracking, which is the standard FCC feed in refineries, and with those of a mixture of VGO (80 wt %) and waxes (20 wt %).

Keywords

FCC W2C ANW